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Опубликовано: 18.09.2023 17:38
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Volume 15 (3), September 2023, Pages 31-37
1Sameddin Gahramanov, 2Khayal Alakbarov, 3Tofig Guliyev, 4Sadagat Heydarova
1Azerbaijan State Research Institute of Occupational Safety and Safety,Chief Engineer, Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
2Azerbaijan State Scientific-Research Institute of Labor Protection and Safety Technology, laboratory director, Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.,
3Azerbaijan State Scientific-Research Institute of Labor Protection and Safety Technology, Candidate of chemical sciences,
4Azerbaijan State Scientific-Research Institute of Labor Protection and Safety Technology, senior researcher, Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра.
ABSTRACT
The article discusses the existing methods of deactivation of pyrophores-iron sulfides, examines their shortcomings, indicates the number, proportions of effective deactivating components and conditions for their use.
A significant part of fires and explosions in the oil, gas and petrochemical industries are caused by self-igniting pyrophores-iron sulfides. The most common iron sulfide compounds in production are FeS, FeS2; F2S3. These compounds, reacting with oxygen in the air, self-ignite and burn, causing a fire, explosion of technical means used in the transportation and storage of oil and petroleum products.
Taking this into account, an effective method of decontamination of pyrophoric deposits has been developed. The proposed composition transforms pyrophoric substances into non-pyrophoric ones, being a foaming agent. The process is characterized by the simplicity of its own method of preparation and use, significantly lower cost.
Pyrophor-a composition passivating iron sulfide, consists of sodium salt (ntnd) naphthenic acid and an aqueous solution of foam-stabilizing polyacrylamide (paa).
Keywords: Pyrophor, iron sulfide compounds, sulfide compounds of petroleum products, naphthenic acids, inhibitors, polyacrylamide (paa), foaming agent reactor.
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Опубликовано: 18.09.2023 17:35
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Автор: Administrator
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Volume 15 (3), September 2023, Pages 22-30
1Yashar Alekberov, 2Ziya Aghayev, 3Ali Ganbarov, 4Javahir Rajabli, 5Aygun Bayramova
1Head of Department, Azerbaijan State Scientific Research Institute of Labor Protection and Safety Technology, Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра., https://orcid.org/0009-0007-5573-318X
2Leading researcher, Azerbaijan State Scientific-Research Institute of Labor Protection and Safety Technology, Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра., https://orcid.org/0009-0001-5591-3822
3Senior researcher, Azerbaijan State Scientific-Research Institute of Labor Protection and Safety Technology, Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра., https://orcid.org/0009-0000-4210-7410
4Scientist, Azerbaijan State Institute of Labor Protection and Safety Technology, Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра., https://orcid.org/0009-0003-6619-9665
5Junior researcher, Azerbaijan State Scientific-Research Institute of Labor Protection and Safety Technology, Этот адрес электронной почты защищён от спам-ботов. У вас должен быть включен JavaScript для просмотра., https://orcid.org/0009-0002-4745-2760
ABSTRACT
The first oil well in the world was drilled in Bibiheybet in 1846 by industrial method (mechanical drilling) and later by drilling in Balakhani in 1871 using impact technology, it turned Azerbaijan into the center of oil production. As a result of the analysis of the country's oil exploration, it was determined that during the past years, over 30,000 oil and gas wells in the land and sea areas have been drilled, and exploited and in the end, their activities were suspended, conserved, or canceled. Currently, the stock of wells in operation is slightly more than 6000. In these processes, environmental imbalances in the areas of oil and gas mines, and pollution of land and water areas, as well as led to the occurrence of serious deviations in the underground.
On the other hand, the technology of decommissioning expired wells requires updating, where not only the cleaning of the polluted oil areas but also the solution to the problems related to the recultivation of the subsoil in the zones are of great importance.
Despite a wide range of scientific research works that have been carried out in the direction of the development of existing methods of decommissioning wells, the issue of the full assurance of the hermeticity of decommissioned wells is considered to be a problem.
On the other hand, the corrosion of protective belts, the absence of cement stone rings behind the belt, as well as the collapse of cement bridges lead to an increase in the probability of the formation of a connection between the productive layers and the ground surface, causing residual oil and gas to flow to the surface in later decommissioned wells [1-3].
For this reason, the presented article is dedicated to the analysis of the current situation of oil well cancellation, restoration, and subsoil recultivation problems and the development of relevant recommendations.
Keywords: oil and gas mines, canceled wells, environmental hazard, underground reclamation, hermeticity.